Chemistry Assignment Help with Equivalent Conductance

9.5 Equivalent Conductance

More precisely, equivalent conductivity of a solution at a dilution V may be defined as the conductance of all the ions produced from one gram equivalent of the electrolyte dissolved in V. Equivalent conductivity is represented by l or

Mathematically, l = k × V

k = Specific conductivity or electrolytic conductivity

V = Volume of solutions in c.c. containing 1 gm equivalent of the electrolyte.

Relationship between equivalent and specific conductivities in terms of concentration Suppose the solution has a concentration of c gram equivalent per litre. Then the volume V containing 1 gram equivalent of the electrolyte will be 1/c litre, i.e.



Therefore, the equation becomes

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