Chemistry Assignment Help With Sulphonation

Sulphonation Assignment Help

It is the process of replacing hydrogen atom by a sulphonic acid group, SO3H. Sulphonation of a normal alkane from hexane onwards may be carried out by treating the alkane with oleum fuming sulphuric acid). The order of ease of replacement of H- atoms in tertiary impounds is very much easier than secondary and in secondary compounds replacement of H-atoms by sulphonic acid group is easier than primary. Replacement of a primary; hydrogen atom in sulphonation is very slow indeed. Isobutane, which contains a tertiary hydrogen atom, is readily sulphonated to give t—butyl sulphonic acid.

(CH3)3CH + H2SO4/SO3 ®(CH3)3CSO3H + H2SO4

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