Oxidative Cleavage Assignment Help

Oxidative Cleavage By Hot Alkaline KMNO4

Alkenes are oxidatively cleaved by hot alkaline permanganate solution. The terminal CH2 up of 1-alkene is is completely oxidized to CO2 and water. A disubstituted atom of a double bond becomes >C = O group of a ketone. A mono substituted atom of a double bond becomes aldehyde up which is further oxidized to salt of carboxylic acid. For example,

(a)

(b)

(c)

(d)

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